表6
Pt…O距离三个配体(H2啊,哦−,)选择Pt (II)配合物。
|
|
配位体 |
5.0 |
20.0 |
61.0 |
|
| ()[葡文(H2O)4]2 + |
H2O |
2.090 |
2.091 |
2.091 |
| ()[葡文(H2O)3(哦)+ |
H2O |
2.143 |
2.132 |
2.131 |
| 哦− |
2.003 |
2.010 |
2.012 |
| ()[葡文(哦)4]2− |
哦− |
2.103 |
2.100 |
2.100 |
| ()[葡文(H2O)3(CF3所以3)]+ |
H2O |
2.108 |
2.103 |
2.101 |
|
|
2.066 |
2.070 |
2.077 |
|
H2O |
2.110 |
2.106 |
2.106 |
| ()[葡文(H2O)2(哦)(CF3所以3)] |
哦− |
2.020 |
2.016 |
2.016 |
|
|
2.169 |
2.175 |
2.175 |
|
|
