研究文章
理论研究从Pt Electrocatalyst溶解度和反应在PEFC Pt的电解液环境复杂
表5
解吸能源(从Pt)的Pt (IV)复合物表面各种介电常数。单位是焦每摩尔。
|
|
5.0 |
20.0 |
61.0 |
|
| ()[葡文(H2O)6]4 + |
58.2 |
138.5 |
177.9 |
| ()[葡文(H2O)5(哦)3 + |
51.1 |
144.0 |
154.8 |
| ()[葡文(H2O)4(哦)2]2 + |
47.3 |
97.1 |
114.2 |
| ()[葡文(H2O)3(哦)3]+ |
2.9 |
30.1 |
50.6 |
| ()[葡文(H2O)2(哦)4] |
−69.1 |
−64.0 |
−60.7 |
| ()[葡文(H2O)5(CF3所以3)]3 + |
72.0 |
191.7 |
216.8 |
| ()[葡文(H2O)4(CF3所以3)2]2 + |
110.1 |
194.2 |
225.2 |
| ()[葡文(H2O)3(CF3所以3)3]+ |
215.5 |
221.8 |
241.1 |
| ()[葡文(H2O)2(CF3所以3)4] |
185.8 |
236.5 |
240.6 |
| ()[葡文(H2O)4(哦)(CF3所以3)]2 + |
126.8 |
158.6 |
169.1 |
| ()[葡文(H2O)3(哦)2(CF3所以3)]+ |
125.1 |
174.1 |
187.9 |
| ()[葡文(H2O)2(哦)3(CF3所以3)] |
−72.4 |
−69.5 |
−67.8 |
| ()[葡文(H2O)3(哦)(CF3所以3)2]+ |
114.3 |
183.3 |
201.7 |
| ()[葡文(H2O)2(哦)2(CF3所以3)2] |
76.2 |
110.1 |
106.3 |
| ()[葡文(H2O)2(哦)(CF3所以3)3] |
165.3 |
189.6 |
227.2 |
|
|
