生物无机化学与应用/2018年/文章/选项卡2

研究文章

合成、结构、DNA相互作用和SOD的活性三镍(II)配合物包含L-Phenylalanine席夫碱和1,10-Phenanthroline

表2

选择键长(A)和键角(°)复合物1,2,3

复杂的1
倪(1)- o (3) 1.990 (2) 倪(1)- n (1) 1.991 (3) 倪(1)- o (1) 2.068 (3)
倪(1)- n (3) 2.075 (3) 倪(1)- n (2) 2.116 (3) 倪(1)- o (4) 2.117 (3)
O(3)镍(1)- n (1) 92.43 (11) O(3)镍(1)- O (1) 173.63 (10) N(1)镍(1)- o (1) 81.29 (11)
O(3)镍(1)- n (3) 93.55 (11) N(1)镍(1)- N (3) 172.77 (11) O(1)镍(1)- n (3) 92.64 (11)
O(3)镍(1)- n (2) 91.84 (11) N(1)镍(1)- N (2) 96.26 (12) O(1)镍(1)- n (2) 87.84 (10)
N(3)镍(1)- N (2) 79.50 (12) O(3)镍(1)- O (4) 89.99 (11) N(1)镍(1)- o (4) 92.72 (11)
O(1)镍(1)- O (4) 91.34 (11) N(3)镍(1)- o (4) 91.33 (11) N(2)镍(1)- o (4) 170.75 (11)

复杂的2
倪(1)- n (1) 1.987 (3) 倪(1)- o (3) 1.997 (3) 倪(1)- o (1) 2.068 (3)
倪(1)- n (3) 2.083 (3) 倪(1)- o (4) 2.100 (3) 倪(1)- n (2) 2.129 (3)
N(1)镍(1)- o (3) 89.99 (12) N(1)镍(1)- o (1) 81.80 (12) O(3)镍(1)- O (1) 171.26 (10)
N(1)镍(1)- N (3) 175.09 (12) O(3)镍(1)- n (3) 94.34 (11) O(1)镍(1)- n (3) 93.75 (11)
N(1)镍(1)- o (4) 90.64 (13) O(3)镍(1)- O (4) 92.52 (12) O(1)镍(1)- O (4) 90.56 (12)
N(3)镍(1)- o (4) 91.50 (13) N(1)镍(1)- N (2) 98.70 (12) O(3)镍(1)- n (2) 90.17 (11)
O(1)镍(1)- n (2) 88.13 (11) N(3)镍(1)- N (2) 78.99 (12) O(4)镍(1)- n (2) 170.29 (12)

复杂的3
倪(1)- n (1) 2.000 (6) 倪(1)- o (3) 2.003 (5) 倪(1)- o (1) 2.053 (5)
倪(1)- n (3) 2.076 (6) 倪(1)- n (2) 2.131 (6) 倪(1)- o (5) 2.146 (5)
倪(2)- n (4) 1.982 (6) 倪(2)- o (8) 1.992 (5) 倪(2)- o (6) 2.059 (5)
倪(2)- n (6) 2.075 (7) 倪(2)- o (10) 2.113 (5) 倪(2)- n (5) 2.116 (6)
倪(3)- n (7) 1.995 (7) 倪(3)o (13) 2.008 (5) 倪(3)o (11) 2.056 (6)
倪(3)- n (8) 2.084 (7) 倪(3)o (15) 2.099 (6) 倪(3)- n (9) 2.114 (7)
N(1)镍(1)- o (3) 92.3 (2) N(1)镍(1)- o (1) 82.0 (2) O(3)镍(1)- O (1) 173.3 (2)
N(1)镍(1)- N (3) 169.9 (2) O(3)镍(1)- n (3) 93.2 (2) O(1)镍(1)- n (3) 92.9 (2)
N(1)镍(1)- N (2) 92.6 (2) O(3)镍(1)- n (2) 96.1 (2) O(1)镍(1)- n (2) 87.8 (2)
N(3)镍(1)- N (2) 78.4 (2) N(1)镍(1)- o (5) 95.3 (2) O(3)镍(1)- O (5) 90.31 (18)
O(1)镍(1)- O (5) 86.70 (19) N(3)镍(1)- o (5) 93.2 (2) N(2)镍(1)- o (5) 169.7 (2)
N(4)倪(2)- o (8) 92.7 (2) N(4)倪(2)- o (6) 81.3 (2) O(8)倪(2)- O (6) 174.0 (2)
N(4)倪(2)- N (6) 171.7 (2) O(8)倪(2)- n (6) 93.3 (2) O(6)倪(2)- n (6) 92.7 (2)
N(4)倪(2)- o (10) 93.9 (2) O(8)倪(2)- O (10) 90.41 (19) O(6)倪(2)- O (10) 89.3 (2)
N(6)倪(2)- o (10) 91.6 (2) N(4)倪(2)- N (5) 95.0 (2) O(8)倪(2)- n (5) 90.8 (2)
O(6)倪(2)- n (5) 90.5 (2) N(6)倪(2)- N (5) 79.3 (3) O(10)倪(2)- n (5) 170.9 (3)
N(7)倪(3)o (13) 91.9 (2) N(7)倪(3)o (11) 80.3 (3) O(13)倪(3)O (11) 171.9 (2)
N(7)倪(3)- N (8) 169.6 (3) O(13)倪(3)- n (8) 96.3 (2) O(11)倪(3)- n (8) 91.6 (2)
N(7)倪(3)o (15) 94.9 (3) O(13)倪(3)O (15) 89.3 (2) O(11)倪(3)O (15) 89.1 (2)
N(8)倪(3)o (15) 91.6 (3) N(7)倪(3)- N (9) 95.4 (3) O(13)倪(3)- n (9) 91.4 (2)
O(11)倪(3)- n (9) 91.6 (2) N(8)倪(3)- N (9) 78.1 (3) O(15)倪(3)- n (9) 169.6 (3)

文章奖:2020年杰出的研究贡献,选择由我们的首席编辑。获奖的文章阅读