研究文章
轴向的结扎锆(IV) Tetraphenylporphyrin:合成、表征和生物活性
表2
光学吸收Zr (TPP)的数据(Y) (X)在不同的溶剂。
|
| 化合物 |
溶剂 |
(nm),(M−1厘米−1) |
(cm−1) |
|
|
|
|
|
|
|
|
|
| 锆(TPP)(中航商用飞机有限公司)(越南河粉) |
丙酮 |
413.1 |
500.5 |
535.7 |
579.9 |
1309.3 |
1067.2 |
0.235887 |
| 5.074 |
4.183 |
4.796 |
5.009 |
|
|
|
| CH2Cl2 |
409.4 |
496.3 |
532.2 |
575.8 |
1241.6 |
1020.7 |
0.197404 |
| 5.030 |
4.126 |
4.721 |
4.951 |
|
|
|
| CHCl3 |
411.3 |
498.5 |
533.4 |
577.5 |
1278.1 |
1041.1 |
0.207468 |
| 5.042 |
4.139 |
4.735 |
4.964 |
|
|
|
|
| 锆(TPP)(中航商用飞机有限公司)(p -哟3越南河粉) |
丙酮 |
414.2 |
501.5 |
536.8 |
580.9 |
1340.2 |
1085.9 |
0.252492 |
| 5.101 |
4.197 |
4.812 |
5.031 |
|
|
|
| CH2Cl2 |
409.8 |
496.4 |
530.6 |
574.9 |
1279.9 |
1039.3 |
0.207586 |
| 5.057 |
4.172 |
4.749 |
4.965 |
|
|
|
| CHCl3 |
411.9 |
498.3 |
534.2 |
578.5 |
1312.6 |
1062.4 |
0.213671 |
| 5.063 |
4.178 |
4.765 |
4.968 |
|
|
|
|
| 锆(TPP)(中航商用飞机有限公司)(pch3越南河粉) |
丙酮 |
412.9 |
501.4 |
535.1 |
580.8 |
1270.3 |
1035.2 |
0.219019 |
| 5.056 |
4.168 |
4.788 |
4.990 |
|
|
|
| CH2Cl2 |
409.7 |
496.3 |
532.3 |
576.4 |
1218.3 |
992.6 |
0.183752 |
| 5.002 |
4.131 |
4.718 |
4.932 |
|
|
|
| CHCl3 |
411.2 |
499.1 |
533.8 |
577.9 |
1236.8 |
1007.9 |
0.194033 |
| 5.012 |
4.147 |
4.729 |
4.949 |
|
|
|
|
| 锆(TPP)(中航商用飞机有限公司)(p-不2越南河粉) |
丙酮 |
410.9 |
500.2 |
536.1 |
582.5 |
1271.2 |
1033.2 |
0.256245 |
| 5.050 |
4.156 |
4.728 |
4.901 |
|
|
|
| CH2Cl2 |
408.6 |
495.2 |
531.5 |
576.3 |
1218.1 |
991.3 |
0.191456 |
| 5.010 |
4.111 |
4.513 |
4.899 |
|
|
|
| CHCl3 |
410.1 |
498.9 |
537.6 |
577.7 |
1235.9 |
1006.7 |
0.198565 |
| 5.006 |
4.124 |
4.279 |
4.999 |
|
|
|
|
| 锆(TPP)(中航商用飞机有限公司)(-naphtholate) |
丙酮 |
413.5 |
500.4 |
535.2 |
581.9 |
1272.3 |
1034.2 |
0.232365 |
| 5.045 |
4.116 |
4.718 |
4.912 |
|
|
|
| CH2Cl2 |
411.5 |
497.8 |
535.6 |
577.6 |
1217.3 |
9956年 |
0.182536 |
| 5.013 |
4.113 |
4.518 |
4.922 |
|
|
|
| CHCl3 |
413.5 |
498.3 |
535.8 |
578.9 |
1235.8 |
1005.3 |
0.195632 |
| 5.102 |
4.127 |
4.739 |
4.948 |
|
|
|
|
|
