表4
溶剂二恶烷对Pd(MME)-CBDCA配合物稳定常数的影响。
|
| 系统 |
%溶剂(v / v) |
米 |
l |
H |
|
|
| -CBDCA Pd (MME) |
12．5 |
0 |
1 |
1 |
6.24 (0.01) |
| 0 |
1 |
2 |
9.76 (0.02) |
| 1 |
0 |
−1 |
−4.07 (0.01) |
| 1 |
0 |
−2 |
−9.63 (0.03) |
| 2 |
0 |
−1 |
−1.08 (0.04) |
| 1 |
1 |
0 |
8.19 (0.03) |
| 1 |
1 |
1 |
10.84 (0.07) |
| 25.0 |
0 |
1 |
1 |
6.86 (0.03) |
| 0 |
1 |
2 |
10.72 (0.05) |
| 1 |
0 |
−1 |
−3.67 (0.09) |
| 1 |
0 |
−2 |
−8.93 (0.02) |
| 2 |
0 |
−1 |
−0.59 (0.09) |
| 1 |
1 |
0 |
8.69 (0.03) |
| 1 |
1 |
1 |
11.64 (0.07) |
| 37.5 |
0 |
1 |
1 |
7.16 (0.01) |
| 0 |
1 |
2 |
11.33 (0.02) |
| 1 |
0 |
−1 |
−3.86 (0.01) |
| 1 |
0 |
−2 |
−9.13 (0.01) |
| 2 |
0 |
−1 |
−0.78 (0.40) |
| 1 |
1 |
0 |
9.07 (0.04) |
| 1 |
1 |
1 |
12.65 (0.06) |
| 50．0 |
0 |
1 |
1 |
7.42 (0.01) |
| 0 |
1 |
2 |
11.85 (0.01) |
| 1 |
0 |
−1 |
−3.87 (0.01) |
| 1 |
0 |
−2 |
−9.40 (0.02) |
| 2 |
0 |
−1 |
−0.43 (0.07) |
| 1 |
1 |
0 |
9.08 (0.04) |
| 1 |
1 |
1 |
13.09 (0.05) |
| 62.5 |
0 |
1 |
1 |
7.88 (0.01) |
| 0 |
1 |
2 |
12.78 (0.02) |
| 1 |
0 |
−1 |
−3.85 (0.02) |
| 1 |
0 |
−2 |
−9.80 (0.02) |
| 2 |
0 |
−1 |
−0.30 (0.04) |
| 1 |
1 |
0 |
9.8 (0.01) |
| 1 |
1 |
1 |
14.08 (0.02) |
|
|
