研究文章
使用2-Pyridinealdoxime / N, N′捐赠者配体结合在钴(III)化学:合成和表征两种阳离子单核钴(ⅲ)配合物
表2
选择债券距离(A)和角度(°)复合物
1
2 h
2O和
2
1.5甲醇,
一个估计标准差的括号。
|
|
1
2 h2O |
2
1.5甲醇 |
|
| 债券的距离 |
|
|
| Co-N () |
1.928 (4) |
1.937 (3) |
| Co-N () |
1.904 (4) |
1.909 (4) |
| Co-N () |
1.986 (4) |
1.977 (4) |
| Co-N () |
1.928 (4) |
1.937 (3) |
| Co-N () |
1.904 (4) |
1.909 (4) |
| Co-N () |
1.986 (4) |
1.977 (4) |
| N ()- O / O () |
1.294 (6) |
1.273 (5) |
| N ()- c () |
1.322 (7) |
1.343 (6) |
| N ()- c () |
1.343 (7) |
1.340 (6) |
| N ()- c (6) |
1.298 (7) |
1.309 (7) |
|
| 键角 |
|
|
| N ()-Co-N (3′) |
82.7 () |
82.2 () |
| N ()-Co-N () |
88.6 () |
93.6 () |
| N ()-Co-N () |
83.7 () |
83.7 () |
| N ()-Co-N () |
89.9 (3) |
89.8 () |
| N ()-Co-N () |
96.1 () |
90.7 () |
| Co-N ()- O / O () |
122.7 (4) |
123.3 (3) |
|
|
未装填的,原子是由对称相关。
|
