|
| 数量 |
生物碱 |
前体离子 |
主要获得的片段在不同CID电压(V)与丰度在不同强度(%) |
|
| (1) |
小檗碱 |
336年 |
10 V |
336 (100),337 (27),321 (5) |
| 20 V |
336 (100),321 (43),292 (22) |
| 30 V |
320 (100),292 (73),321 (69),306 (26) |
| 40 V |
320 (100),278 (55),292 (49),318 (31)、306 (25) |
| 50 V |
278 (100),318 (38),292 (31),279 (2) |
| 60 V |
278 (100),263 (31),249 (27),220 (26) |
| 80 V |
191 (100),220 (47),204 (46)、192 (38) |
|
| (2) |
Magnoflorine |
342年 |
10 V |
342 (100),343 (31),297 (12),58 (10) |
| 20 V |
297 (100),265 (85),342 (78),58 (71) |
| 30 V |
58 (100),265 (29),297 (16) |
| 40 V |
58 (100),191 (31)、222 (29) |
| 50 V |
58 (100),179 (20),192 (10) |
| 60 V |
58 (100),165 (56),176 (20) |
| 80 V |
58 (100),165 (50)、178 (40) |
|
| (3) |
血根碱 |
332年 |
10 V |
332 (100),333 (27),334 (3) |
| 20 V |
332 (100),333 (24),304 (7) |
| 30 V |
332 (100),274 (41),304 (39)、317 (34) |
| 40 V |
274 (100),304 (60),246 (52),216 (30) |
| 50 V |
304 (100),216 (55),246 (48),189 (22) |
| 60 V |
246 (100),216 (60),260 (40)、189 (30) |
| 80 V |
189 (100),202 (85),176 (75) |
|
| (4) |
小檗胺 |
609年 |
10 V |
609 (100),610 (38),611 (35)、612 (16) |
| 20 V |
609 (100),611 (76),206 (29),579 (12) |
| 30 V |
609 (100),611 (80),192 (80),578 (69),206 (64),296 (45) |
| 40 V |
206 (100),192 (93),174 (36),190 (34)、296 (34) |
| 50 V |
206 (100),192 (90),296 (52),239 (41) |
| 60 V |
206 (100),192 (62),174 (47),296 (40) |
| 80 V |
160 (100),191 (94),165 (85),174 (84) |
|
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