研究文章
表面活性剂对协会的影响特点,Di - Triblock共聚物的氧乙烯和Oxybutylene水解决方案:稀溶液相图,SANS,在不同的温度和粘度测量
表1
浊度分Tp和云点,Cpcopolymers-surfactants混合物*解决方案。
|
| 浓缩的。,b - 1 |
SDS |
浓缩的。,b - 2 |
SDS |
|
Tp°C |
Cp°C |
|
Tp°C |
Cp°C |
|
|
0 |
0.001 |
0.05 |
1.0 |
0 |
0.001 |
0.05 |
1.0 |
|
0 |
0.0005 |
0.05 |
1.0 |
0 |
0.0005 |
0.05 |
1.0 |
| 1.0 |
51.0 |
58.0 |
80.0 |
> 100 |
58.0 |
82.0 |
> 100 |
> 100 |
1.0 |
79.0 |
80.0 |
> 100 |
> 100 |
83.0 |
85.0 |
> 100 |
> 100 |
| 2.0 |
51.0 |
57.0 |
68.0 |
> 100 |
60.0 |
80.0 |
> 100 |
> 100 |
2.0 |
73.0 |
75.0 |
> 100 |
> 100 |
84.0 |
86.0 |
> 100 |
> 100 |
| 5.0 |
52.0 |
52.0 |
53.0 |
> 100 |
61.0 |
60.0 |
62.0 |
> 100 |
5.0 |
72.0 |
73.5 |
78.0 |
> 100 |
85.0 |
85.0 |
93.0 |
> 100 |
| 7.5 |
- - - - - - |
50.0 |
54.0 |
> 100 |
- - - - - - |
61.0 |
63.0 |
> 100 |
7.5 |
- - - - - - |
69.0 |
75.0 |
> 100 |
- - - - - - |
87.0 |
91.0 |
> 100 |
| 10.0 |
53.0 |
53.0 |
55.0 |
> 100 |
62.0 |
63.0 |
64.0 |
> 100 |
10.0 |
63.0 |
65.0 |
72.0 |
> 100 |
86.0 |
88.0 |
89.0 |
> 100 |
|
|
DTAB |
|
DTAB |
|
|
|
0.05 |
0.10 |
1.0 |
|
0.05 |
0.10 |
1.0 |
|
|
0.0005 |
0.1 |
1.0 |
|
|
|
|
| 1.0 |
|
54.0 |
66.0 |
> 100 |
|
68.0 |
90.0 |
> 100 |
1.0 |
|
80.0 |
> 100 |
> 100 |
|
85.0 |
> 100 |
> 100 |
| 2.0 |
|
56.0 |
62.0 |
> 100 |
|
76.0 |
88.0 |
> 100 |
2.0 |
|
74.0 |
> 100 |
> 100 |
|
89.0 |
> 100 |
> 100 |
| 5.0 |
|
54.0 |
57.0 |
> 100 |
|
68.0 |
68.0 |
> 100 |
5.0 |
|
73.0 |
82.0 |
> 100 |
|
84.0 |
> 100 |
> 100 |
| 7.5 |
|
52.0 |
56.0 |
> 100 |
|
64.0 |
66.0 |
> 100 |
7.5 |
|
68.0 |
76.0 |
> 100 |
|
86.0 |
92.0 |
> 100 |
| 10.0 |
|
53.5 |
54.0 |
> 100 |
|
65.0 |
65.0 |
> 100 |
10.0 |
|
65.0 |
73.0 |
> 100 |
|
87.0 |
89.0 |
> 100 |
|
|
tx - 100 |
|
tx - 100 |
|
|
|
0.01 |
3.0 |
6.0 |
|
0.01 |
3.0 |
6.0 |
|
|
0.01 |
3.0 |
6.0 |
|
0.01 |
3.0 |
6.0 |
| 1.0 |
|
52.0 |
52.0 |
48.0 |
|
59.0 |
64.0 |
65.5 |
1.0 |
|
75.0 |
63.0 |
59.0 |
|
85.0 |
80.0 |
76.0 |
| 2.0 |
|
51.5 |
54.0 |
49.0 |
|
58.0 |
68.0 |
66.0 |
2.0 |
|
73.5 |
60.0 |
58.0 |
|
82.0 |
77.0 |
75.0 |
| 5.0 |
|
52.5 |
51.0 |
48.5 |
|
59.0 |
63.0 |
65.0 |
5.0 |
|
71.0 |
59.0 |
57.0 |
|
80.0 |
76.0 |
73.0 |
| 7.5 |
|
51.0 |
49.0 |
47.5 |
|
58.0 |
59.0 |
64.5 |
7.5 |
|
70.0 |
57.0 |
56.0 |
|
79.0 |
75.0 |
72.0 |
| 10.0 |
|
53.0 |
48.0 |
47.0 |
|
60.0 |
60.0 |
65.0 |
10.0 |
|
69.0 |
56.0 |
54.0 |
|
78.0 |
74.0 |
71.0 |
|
|
*浓缩的。(g·dl−1)。
|