研究文章
平衡和动态调查模型铂(II)复杂的相互作用与DNA的抗肿瘤活性成分:复杂地层的反应(Pd (N, N-diethylethylenediamine) (H2O)2]2 +配体的生物学意义和位移反应的DNA成分
表1
复合物的形成常数(Pd(宗教)(H2O)2]2 +氨基酸在37岁和0.16离子强度。
|
| 配位体 |
毫升 |
|
配位体 |
M L |
|
|
| 哦- - - - - - |
1 01 |
5.11 (0.01) |
甘氨酸 |
0 1 1 |
9.20 (0.02) |
|
1 02 |
14.80 (0.02) |
|
0 1 2 |
11.20 (0.03) |
|
2 02 |
7.20 (0.04) |
|
1 1 0 |
10.33 (0.02) |
| 丙氨酸 |
0 1 1 |
9.27 (0.01) |
β苯丙氨酸 |
0 1 1 |
9.12 (0.01) |
|
0 1 2 |
12.17 (0.02) |
|
0 1 2 |
11.01 (0.03) |
|
1 1 0 |
10.16 (0.02) |
|
1 1 0 |
9.86 (0.02) |
| γ氨基丁酸酸 |
0 1 1 |
9.63 (0.00) |
β丙氨酸 |
0 1 1 |
9.70 (0.02) |
|
0 1 2 |
13.10 (0.02) |
|
0 1 2 |
13.20 (0.03) |
|
1 1 0 |
7.61 (0.02) |
|
1 1 0 |
9.50 (0.02) |
| 缬氨酸 |
0 1 1 |
9.01 (0.01) |
脯氨酸 |
0 1 1 |
10.06 (0.01) |
|
0 1 2 |
11.48 (0.02) |
|
0 1 2 |
11.81 (0.05) |
|
1 1 0 |
9.90 (0.03) |
|
1 1 0 |
10.51 (0.10) |
| Iso-Leucine |
0 1 1 |
9.46 (0.01) |
组胺 |
0 1 1 |
9.34 (0.01) |
|
0 1 2 |
11.74 (0.02) |
|
0 1 2 |
15.20 (0.02) |
|
1 1 0 |
10.40 (0.02) |
|
1 1 0 |
12.85 (0.08) |
| 组氨酸 |
0 1 1 |
8.84 (0.01) |
乙醇胺 |
0 1 1 |
9.16 (0.01) |
|
0 1 2 |
14.74 (0.02) |
|
1 1 0 |
6.99 (0.02) |
|
0 1 3 |
16.81 (0.06) |
|
1 2 0 |
12.00 (0.04) |
|
1 1 0 |
13.37 (0.01) |
|
1 1 1 |
2.01 (0.04) |
|
1 1 1 |
16.32 (0.03) |
|
|
(= 4.98) |
| 丝氨酸 |
0 1 1 |
8.59 (0.01) |
苏氨酸 |
0 1 1 |
8.79 (0.01) |
|
0 1 2 |
10.95 (0.02) |
|
0 1 2 |
10.85 (0.02) |
|
1 1 0 |
10.01 (0.01) |
|
1 1 0 |
9.98 (0.07) |
|
1号1 - 1 |
2.04 (0.02) |
|
1号1 - 1 |
2.10 (0.08) |
|
|
(= 7.97) |
|
|
(= 7.88) |
| 鸟氨酸 |
0 1 1 |
9.81 (0.02) |
赖氨酸 |
0 1 1 |
9.90 (0.02) |
|
0 1 2 |
18.16 (0.02) |
|
0 1 2 |
18.80 (0.03) |
|
0 1 3 |
20.01 (0.03) |
|
0 1 3 |
21.00 (0.03) |
|
1 1 0 |
12.90 (0.05) |
|
1 1 0 |
10.12 (0.05) |
|
1 1 1 |
20.10 (0.04) |
|
1 1 1 |
18.70 (0.02) |
| 天冬氨酸 |
0 1 1 |
9.31 (0.02) |
谷氨酸 |
0 1 1 |
9.34 (0.02) |
|
0 1 2 |
12.79 (0.03) |
|
0 1 2 |
13.15 (0.03) |
|
0 1 3 |
14.50 (0.03) |
|
0 1 3 |
15.73 (0.05) |
|
1 1 0 |
8.53 (0.03) |
|
1 1 0 |
8.70 (0.03) |
|
1 1 1 |
11.92 (0.04) |
|
1 1 1 |
11.87 (0.02) |
| S-methylcysteine甲基酯 |
0 1 1 |
8.51 (0.02) |
蛋氨酸 |
0 1 1 |
8.76 (0.02) |
|
0 1 2 |
10.40 (0.02) |
|
0 1 2 |
11.00 (0.03) |
|
1 1 0 |
9.51 (0.01) |
|
1 1 0 |
9.32 (0.04) |
| 羟脯氨酸 |
0 1 1 |
9.20 (0.01) |
甲胺 |
0 1 1 |
9.32 (0.01) |
|
0 1 2 |
11.00 (0.02) |
|
1 1 0 |
7.11 (0.06) |
|
1 1 0 |
9.91 (0.03) |
|
1 2 0 |
12.53 (0.04) |
| 半胱氨酸 |
0 1 1 |
10.00 (0.01) |
|
|
|
|
0 1 2 |
18.21 (0.02) |
|
|
|
|
0 1 3 |
19.62 (0.02) |
|
|
|
|
1 1 0 |
14.11 (0.03) |
|
|
|
|
|
18.20 (0.04) |
|
|
|
|
|
、L、H是化学计量系数对应于Pd(宗教),氨基酸,分别;系数1,指的是一个质子的损失。Pd(宗教)的胺基酸。标准差在括号给出;残差平方的总和小于5 e -,
|
