TY - JOUR A2 - 拉玛克里斯纳,Doraiswami AU - Tsamo,科尼利厄斯AU - Paltahe,阿巴AU - Fotio,丹尼尔AU - 文森特,撕毁阿坦加纳AU - 销售,Wassansa弗朗索瓦PY - 2019 DA - 2019年11月27日TI - 单,有限公司二和三参数等温线,动力学,热力学和评估(II)水溶液中使用死楝树叶SP删除 - 6452672 VL - 2019 AB - 水重金属的污染,如CO(II)是特别的关注,因为他们在环境,毒性和能力的有机体生物累积的持久性。在这项研究中,接触时间在三个初始浓度,pH,吸附剂剂量,温度和动力学,热力学,影响和一,二,Co对楝树叶吸附(II)和三参数等温线模型(DNL)进行了研究。使用FTIR,TGA-DSC,EDX,和氮吸附 - 解吸的吸附剂进行了表征。DNL is composed of many Co(II) surface-binding groups and a BET surface area of 0.2783 m2/克通过孔和大孔支配。平衡,达到在10分钟内的三个浓度的85-97的%A去除效率。Δ G° of −5.424 to −6.068 KJ/mol at 25 to 60°C, respectively, indicated spontaneous adsorption with increasing temperature. D-R adsorption energies of 0.649 to 2.433 KJ/mol revealed physical adsorption. Maximum adsorption capacity of 9.201–523.900 mg/g was obtained by Freundlich and Jovanovic isotherms. Adsorption was very favourable as evident by the high Kiselev equilibrium constant (11.652–172.78 L/mg) and very low [R 大号的0.001-0.026值。Adsorption occurred by repulsive mechanism as indicated by Fowler–Guggenheim and Hill–de Boer negative interaction energies (−16.182 to −90.163 and −111.102 to −3328.86 KJmol-1 分别),证实最大的Co(II)的吸附在pH为3的结果可以在使用楝树叶的有效吸附系统,该系统是在除去低和高含量的重金属等从废水中的钴离子的非常高效的设计中使用。SN - 1687-806X UR - https://doi.org/10.1155/2019/6452672 DO - 10.1155 /六百四十五万二千六百七十二分之二千○一十九JF - 国际期刊化学工程PB - Hindawi出版KW - ER -