生物无机化学与应用
研究文章

双核的铜(II)和(II)配合物有三叉的杂环与4-Aminoantipyrine Shiff基础来源于水杨醛

表3

结构参数、债券(°),长度和角度(°)的铜2(L2)2(H2O)4复杂的。
参数
债券的长度(°) 键角(°)
铜(136)- o (138)
铜(135)- o (137)
O(134)铜(135)
O(129)铜(135)
O(129)铜(136)
N(125)铜(136)
O(116)铜(136)
O(110)铜(136)
O(105)铜(136)
O(105)铜(135)
N(101)铜(135)
O(92)铜(135)
铜(50)- o (52)
铜(49)- o (51)
O(48)铜(49)
C (47) - o (48)
C (46) - h (82)
C (46) - C (47)
C (45) - h (81)
C (45) - C (46)
C (44) - h (80)
C (44) - C (45)
O(43)铜(49)
O(43)铜(50)
O(30)铜(50)
C (29) - C (37)
C (28) - n (39)
C (28) - C (29)
C (27) - o (30)
C (27) - C (28)
N (26) - c (31)
N (26) - c (27)
N (25) - c (38)		 1.5230
1.5230
2.0400
2.3621
1.9129
2.3774
1.8092
1.3403
1.8419
1.7708
1.3875
1.5551
1.5228
1.5227
2.0398
1.4033
1.1000
1.0149
1.1000
1.1328
1.1000
1.0148
2.3617
1.9130
1.8090
1.0468
1.0144
1.1317
1.1265
0.9997
0.9735
1.0636
0.9597		 O(19)铜(50)- O - h (85) (52)
O(19)铜(50)- O - h (86) (52)
O(24)铜(50)- O - h (85) (52)
O(24)铜(50)- O - h (86) (52)
O(30)铜(50)- O - h (85) (52)
O(30)铜(50)- O - h (86) (52)
N(39)铜(50)- o - h (85) (52)
N(39)铜(50)- o - h (86) (52)
O(43)铜(50)- O - h (85) (52)
O(43)铜(50)- O - h (86) (52)
O(6)铜(49)- O (51) - h (83)
O(6)铜(49)- O (51) - h (84)
N(15)铜(49)- o (51) - h (83)
N(15)铜(49)- o (51) - h (84)
O(19)铜(49)- O (51) - h (83)
O(19)铜(49)- O (51) - h (84)
O(43)铜(49)- O (51) - h (83)
O(43)铜(49)- O (51) - h (84)
O(48)铜(49)- O (51) - h (83)
O(48)铜(49)- O (51) - h (84)
C (47) - o(48)铜(49)- o (6)
C (47) - o(48)铜(49)- n (15)
C (47) - o(48)铜(49)- o (19)
C (47) - o(48)铜(49)- o (43)
C (47) - o(48)铜(49)- o (51)
铜(50)- o(43)铜(49)- o (48)
铜(50)- o(43)铜(49)- o (51)
C (42) - o(43)铜(50)- o (19)
C (42) - o(43)铜(50)- o (24)
C (42) - o(43)铜(50)- o (30)
C (42) - o(43)铜(50)- n (39)
C (42) - o(43)铜(50)- o (52)
铜(49)- o(43)铜(50)- o (19)
铜(49)- o(43)铜(50)- o (24)
铜(49)- o(43)铜(50)- o (30)		 179.9998
−0.0001
174.1519
−5.8480
−40.8405
139.1596
9.7808
−170.2191
−3.4183
176.5818
−179.9999
0.0011
−122.7109
57.2900
41.5484
−138.4507
37.5946
−142.4044
37.5946
142.4044
−155.1509
−34.7220
55.8245
52.8179
−127.1821
180.000
180.000
−150.107
−143.209
66.7882
18.0306
32.7885
−2.8955
4.0021
−146.00